131508-65-1Relevant academic research and scientific papers
New methodology for the differentiation of the primary hydroxyl groups in 2,3,3′,4,4′-penta-O-benzylsucrose: Convenient approach to sucrose monophosphines
Burdynska, Joanna,Lewandowski, Bartosz,Jarosz, Slawomir
experimental part, p. 403 - 415 (2012/06/01)
Two new routes to derivatives of 2,3,3′,4,4′-penta-O- benzylsucrose with differently protected primary hydroxyl groups were elaborated. One of these compounds, 2,3,3′,4,4′-penta-O-benzyl- 6′-O-mesylsucrose, was used in a model synthesis of the 6′-phosphine with sucrose scaffold. Elimination of the mesyloxy-group under the reaction conditions was also noted providing the 5′,6′-unsaturated sucrose derivative. Copyright Taylor & Francis Group, LLC.
