131520-01-9Relevant academic research and scientific papers
REACTION OF ORGANYLTHIOCHLOROACETYLENES WITH ORGANYLSELENOLS
Martynov, A. V.,Seredkina, S. G.,Mirskova, A. N.
, p. 1693 - 1699 (2007/10/02)
The reaction of organylthiochloroacetylenes RSCαCβCl with selenols in a DMSO solution containing KOH leads to organylthio(organylseleno)acetylenes RSCCSeR'.When the reaction of organylthiochloroacetylenes with selenols was carried out in diethyl ether, the previously unknown 1-organylthio-2-organylseleno-2-chloroethenes RSCH=CClSeR' were obtained in the form of Z- and E-isomers.The hydrochlorination of organylthio(organylseleno)acetylenes results in Z- and E-1-organylthio-2-organylseleno-1-chloroethenes RSCCl=CHSeR'.
