1315277-67-8Relevant articles and documents
Transition-metal-free hydroboration of terminal alkynes activated by base
Hong, Shibin,Zhang, Wei,Liu, Mengyan,Yao, Zi-Jian,Deng, Wei
, p. 1 - 4 (2016)
Transition-metal and ligand-free method for the hydroboration of terminal alkynes with B2pin2 was reported in LiOt-Bu/toluene/MeOH system under room temperature. Alkylalkynes and arylalkynes reacted efficiently with high regioselecti
Neosilyllithium-Catalyzed Hydroboration of Alkynes and Alkenes in the Presence of Pinacolborane (HBpin)
Kumar, Gobbilla Sai,Moorthy, Shruti,Karmakar, Himadri,Singh, Saurabh Kumar,Panda, Tarun K.
supporting information, (2021/11/13)
We report here a novel protocol for the hydroboration of alkynes and alkenes, which in the presence of neosilyllithium (LiCH2SiMe3) (5 mol %) and pinacolborane efficiently results in the formation of corresponding alkenyl and alkyl b
Copper-Photocatalyzed Hydroboration of Alkynes and Alkenes
Zhong, Mingbing,Gagné, Yohann,Hope, Taylor O.,Pannecoucke, Xavier,Frenette, Mathieu,Jubault, Philippe,Poisson, Thomas
supporting information, p. 14498 - 14503 (2021/05/21)
The photocatalytic hydroboration of alkenes and alkynes is reported. The use of newly-designed copper photocatalysts with B2Pin2 permits the formation a boryl radical, which is used for hydroboration of a large panel of alkenes and a
Cs4B4O3F10: First Fluorooxoborate with [BF4] Involving Heteroanionic Units and Extremely Low Melting Point
Xia, Ming,Mutailipu, Miriding,Li, Fuming,Yang, Zhihua,Pan, Shilie
supporting information, p. 9753 - 9757 (2021/05/27)
Herein, a new congruently melting mixed-anion compound Cs4B4O3F10 has been characterized as the first fluorooxoborate with [BF4] involving heteroanionic units. Compound Cs4B4O3F10 possesses two highly fluorinated anionic clusters and therefore its formula can be expressed as Cs3(B3O3F6) ? Cs(BF4). The influence of [BF4] units on micro-symmetry and structural evolution was discussed based on the parent compound. More importantly, Cs4B4O3F10 shows the lowest melting point among all the available borates and thus sets a new record for such system. This work is of great significance to enrich and tailor the structure of borates using perfluorinated [BF4] units.