13153-97-4Relevant academic research and scientific papers
A PHENYLCARBENE TRANSFER SYSTEM
Cunico, Robert F.,Chu, Kuang S.
, p. 271 - 278 (2007/10/02)
Treatment of (α,α-dichlorobenzyl)trimethylsilane with potassium fluoride/18-crown-6 ether/diglyme transfers phenylchlorocarbene to a number of carbenophiles at room temperature.
HAMMETT ANALYSIS OF ABSOLUTE CARBENE ADDITION RATE CONSTANTS
Moss, R.A.,Perez, L.A.,Turro, N.J.,Gould, I.R.,Hacker, N.P.
, p. 685 - 688 (2007/10/02)
Absolute rate constants were determined for the additions of 5 p-X-substituted ArCCl (X=CF3, Cl, H, CH3, CH3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ= +1.4 - 1.6.
