13154-00-2Relevant academic research and scientific papers
A PHENYLCARBENE TRANSFER SYSTEM
Cunico, Robert F.,Chu, Kuang S.
, p. 271 - 278 (2007/10/02)
Treatment of (α,α-dichlorobenzyl)trimethylsilane with potassium fluoride/18-crown-6 ether/diglyme transfers phenylchlorocarbene to a number of carbenophiles at room temperature.
MECHANISM OF C-H INSERTION OF CARBENE IN RIGID MATRIX
Tomioka, Hideo,Ozaki, Yasuji,Izawa, Yasuji
, p. 843 - 846 (2007/10/02)
C-H insertion process of phenylchlorocarbene, a ground state singlet carbene, is not affected by matrix which generally exerts its effect in C-H insertion of most arylcarbenes.This reveals the origin of the matrix effects on carbene reactions.
