1315475-95-6Relevant academic research and scientific papers
A Suzuki-type cross-coupling reaction of arylacetylene halides with arylboronic acids
Shi, Yu,Li, Xiaoyu,Liu, Jianhui,Jiang, Wenfeng,Sun, Licheng
experimental part, p. 514 - 520 (2012/04/04)
A PdCl2-catalyzed direct alkynylation of arylboronic acids to give diarylacetylenes is described. The optimal conditions using PdCl 2 as catalyst, MeOH-PhMe-H2O as solvent and K 2CO3 as base effectively suppressed the formation of homo-coupling product and afforded moderate to good yield of the desired unsymmetrical coupling product. This reaction represents a Suzuki-type sp 2(C-B)-sp(C-X) cross-coupling. Copyright
