1315481-62-9

Basic information

• Product Name: Pd(C₆H₄F-p)[2,6-(tBu₂PO)2C₆H₃]
• CAS NO: 1315481-62-9
• Molecular Weight: 599.014
• Mol File: 1315481-62-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pd(C₆H₄F-p)[2,6-(tBu₂PO)2C₆H₃](CAS DataBase Reference)
• NIST Chemistry Reference: Pd(C₆H₄F-p)[2,6-(tBu₂PO)2C₆H₃](1315481-62-9)
• EPA Substance Registry System: Pd(C₆H₄F-p)[2,6-(tBu₂PO)2C₆H₃](1315481-62-9)

Safety Data

• Hazardous Substances Data: 1315481-62-9(Hazardous Substances Data)

Upstream product

• 13716-10-4 di(tert-butyl)chlorophosphine 
• 1315481-56-1 [2,6-(^tBu₂PO)₂C₆H₃]PdCl 
• 108-46-3 recorcinol 
• 925706-65-6 resorcinolbis[(di-t-butyl)phosphinite] palladium trifluoroacetate 
• 1493-23-8 (4-fluorophenyl)lithium 

Relevant articles and documents

Synthesis and characterization of fluorophenylpalladium pincer complexes: Electronic properties of some pincer ligands evaluated by multinuclear NMR spectroscopy and electrochemical studies

Palladium fluorophenyl complexes with different pincer ligands Pd(Ar)[2,6-(tBu2PCH2)2C6H 3] (13), Pd(Ar)[2,6-(tBu2PO)2C 6H3] (14), Pd(Ar)[{2,5-(tBu2PCH 2)2C5H2}Fe(C5H 5)] (15), and Pd(Ar)[{2,5-(tBu2PCH2) 2C5H2}Ru(C5H5)] (16) were synthesized by the reaction of LiAr (Ar = C6H4F-4) with the respective trifluoroacetate palladium pincer complexes 9-12. The molecular structures of 14 and 16 were determined by an X-ray crystallographic method. Complexes 13-16 and {Pd(Ar)[{2,5-(tBu2PCH2) 2C5H2}Fe(C5H5)]}PF 6 (17) were studied by multinuclear NMR spectroscopy and cyclic voltammetry. On the basis of 19F NMR chemical shifts and 1J(13C-19F) coupling constants, as well as PdII/PdIV oxidation potentials, electronic characteristics of the corresponding pincer ligands were elucidated.