131549-99-0

Basic information

• Product Name: [(4R,4aR,6R,7S,7aS)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-7-phenyl-tetrahydro-furo[3,2-d][1,3]dioxin-6-ylmethyl]-trimethyl-silane
• Synonyms: [(4R,4aR,6R,7S,7aS)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-7-phenyl-tetrahydro-furo[3,2-d][1,3]dioxin-6-ylmethyl]-trimethyl-silane
• CAS NO: 131549-99-0
• Molecular Weight: 420.621
• Mol File: 131549-99-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(4R,4aR,6R,7S,7aS)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-7-phenyl-tetrahydro-furo[3,2-d][1,3]dioxin-6-ylmethyl]-trimethyl-silane(CAS DataBase Reference)
• NIST Chemistry Reference: [(4R,4aR,6R,7S,7aS)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-7-phenyl-tetrahydro-furo[3,2-d][1,3]dioxin-6-ylmethyl]-trimethyl-silane(131549-99-0)
• EPA Substance Registry System: [(4R,4aR,6R,7S,7aS)-4-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-7-phenyl-tetrahydro-furo[3,2-d][1,3]dioxin-6-ylmethyl]-trimethyl-silane(131549-99-0)

Safety Data

• Hazardous Substances Data: 131549-99-0(Hazardous Substances Data)

Upstream product

• 40595-34-4 (E)-trimethyl(3-phenylallyl)silane 
• 13039-93-5 2,2:4,5-di-O-isopropylidene-D-arabinose 

Downstream Products

• 131550-00-0 Acetic acid (2S,3S,4S,5R)-2-acetoxymethyl-4-phenyl-5-trimethylsilanylmethyl-tetrahydro-furan-3-yl ester 

Relevant articles and documents

Structural elucidation of the cyclic products formed by the reaction of 2,3-O-isopropylidene derivatives of aldehydo-aldose with allylsilanes, vinyl ethers, or vinyl sulfides in the presence of boron trifluoride etherate

The structural elucidation of the cyclic products derived from 2,3-O-isopropylidene derivatives of aldehydo-aldose and allylsilanes, vinyl ethers, or vinyl sulfides indicated that tetrahydrofuran derivatives were formed by cyclization accompanied with migration of the isopropylidene group.