13155-83-4

Basic information

• Product Name: dimethyl exotricyclonona-3,7-diene-3,4-dicarboxylate
• Synonyms: dimethyl exotricyclonona-3,7-diene-3,4-dicarboxylate;Dimethyl exo-tricyclo[4.2.1.02,5]nona-3,7-diene-3,4-dicarboxylate
• CAS NO: 13155-83-4
• Molecular Formula: C₁₃H₁₄O₄
• Molecular Weight: 234.24786
• Mol File: 13155-83-4.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• Refractive Index: 1.567
• CAS DataBase Reference: dimethyl exotricyclonona-3,7-diene-3,4-dicarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: dimethyl exotricyclonona-3,7-diene-3,4-dicarboxylate(13155-83-4)
• EPA Substance Registry System: dimethyl exotricyclonona-3,7-diene-3,4-dicarboxylate(13155-83-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39
• Hazardous Substances Data: 13155-83-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H14O4/c1-16-12(14)10-8-6-3-4-7(5-6)9(8)11(10)13(15)17-2/h3-4,6-9H,5H2,1-2H3/t6-,7+,8+,9-

Upstream product

• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 
• 762-42-5 dimethyl acetylenedicarboxylate 
• 278-06-8 quadricyclo[2.2.1.0.0]heptane 
• 278-06-8 tetracyclo-[3.2.0.0.^2,7.0^4,6]heptane 

Downstream Products

• 1380336-52-6 C₆₀H₆₄O₁₄S₄ 
• 1380336-51-5 C₆₄H₇₂O₁₀ 
• 73500-16-0 1-benzyl-1H-[1,2,3]triazole-4,5-dicarboxylic acid dimethyl ester 
• 71928-61-5 tetramethyl (1α,2β,5β,6α,7β,10β)tetracyclo[4.4.1.0^2,5.0^7,10]undec-3,8-diene-3,4,8,9-tetracarboxylate 

Relevant articles and documents

The influence of the framework: An anion-binding study using fused [n]polynorbornanes

A series of bis-thiourea-functionalized [n]polynorbornane hosts (1-6) with increasing size were synthesized and their anion-binding properties were evaluated by using 1HNMR spectroscopic titration and Job's plot analysis. The larger bis-thiourea-[3]polynorbornane scaffolds 4 and 5 bound acetate in a 1:1 (cooperative) arrangement, whereas the corresponding smaller norbornane host 2, identical in preorganization, bound acetate in a 1:2 (independent) arrangement. In contrast, the size of the framework had no influence on the binding of dihydrogenphosphate. These results clearly highlight the subtle influence that the framework itself can have on host-guest interactions. One anion or two? A series of bis-thiourea-functionalized [n]polynorbornane hosts (1-6) with increasing size were synthesized and their anion-binding properties were evaluated by using 1HNMR spectroscopic titration and Job's plot analysis. Our results highlight the subtle influence that the framework itself can have on host-guest interactions.

Microwave-accelerated ruthenium-catalyzed [2π+2π] cycloadditions of dimethylacetylene dicarboxylate with norbornenes

An efficient and convenient procedure has been developed for the ruthenium-catalyzed [2π+2π] cycloadditions of dimethylacetylene dicarboxylate with norbornenes. Reaction is significantly accelerated in microwave conditions, while the commonly used benzene

Rhenium-catalyzed [2 + 2] cycloadditions of norbornenes with internal and terminal acetylenes

Treatment of norbornenes with internal and terminal acetylenes in the presence of a catalytic amount of [ReBr(CO)3(thf)]2 gave cyclobutene derivatives in good to excellent yields. Copyright