1315552-22-7Relevant academic research and scientific papers
3D and 2D supramolecular assemblies and thermotropic behaviour of a: Carbo -benzenic mesogen
Zhu, Chongwei,Wang, Tsai-Hui,Su, Chien-Jhang,Lee, Shern-Long,Rives, Arnaud,Duhayon, Carine,Kauffmann, Brice,Maraval, Valérie,Chen, Chun-Hsien,Hsu, Hsiu-Fu,Chauvin, Remi
, p. 5902 - 5905 (2017)
Hexaalkoxy-di(phenylethynyl)-tetraphenyl-carbo-benzenes bearing six CnH2n+1 aliphatic chains (n = 12, 18) have been synthesized and characterized, including by single crystal XRD analysis. For n = 12, a liquid crystal behaviour was observed in the range of 109-130 °C. DSC, POM and PXRD analyses evidenced a rectangular columnar mesophase at 115 °C. The determined 3D lattice constants are consistent with 2D STM images of the so-called carbo-mesogen deposited on an HOPG surface.
