1315564-08-9Relevant academic research and scientific papers
Non-Cp titanium alkoxide-based homolytic ring-opening of epoxides by an intramolecular hydrogen abstraction in β-titanoxy radical intermediates
Kawaji, Tsuyoshi,Shohji, Noriaki,Miyashita, Kenji,Okamoto, Sentaro
, p. 7857 - 7859 (2011/09/15)
A low-valent titanium species derived in situ from Ti(O-i-Pr)4, Me3SiCl and Mg powder in tetrahydrofuran reacted with epoxides to selectively provide less hindered alcohols via a homolytic ring-opening of epoxides, in which the intermediate β-titanoxy radical intramolecularly abstracted a hydrogen atom from an alkoxy moiety in the titanium complexes.
