131617-94-2Relevant academic research and scientific papers
Manganese(III)-Based Asymmetric Oxidative Free-Radical Cyclization of Unsaturated β-Keto Sulfoxides
Snider, Barry B.,Wan, Barbara Yu-Fong,Buckman, Brad O.,Foxman, Bruce M.
, p. 328 - 334 (2007/10/02)
β-Keto sulfoxides and β-keto sulfones can be used as substrates for Mn(III)- and Cu(II)-based oxidative free-radical cyclizations.The sulfoxide chiral center completely controls the stereochemistry of the cyclization.Oxidative cyclization of racemic sulfo
