131636-10-7Relevant academic research and scientific papers
Enantioselective synthesis of pumiliotoxin 251D. A strategy E employing an allene-based electrophile-mediated cyclization
Fox, David N. A.,Lathbury, David,Mahon, Mary F.,Molloy, Kieran C.,Gallagher, Timothy
, p. 2652 - 2656 (2007/10/02)
The enantioselective synthesis of pumiliotoxin 251D (1) (nine steps, 6.3% overall yield) is described in which the Pd11-mediated cyclization of the optically pure allenic amine 6 to give pyrrolidine 7a plays a central role. The functionality th
