131656-37-6

Basic information

• Product Name: {MnRe(CO)6(η-S2CP(C6H11)3)}
• Synonyms: {MnRe(CO)6(η-S2CP(C6H11)3)}
• CAS NO: 131656-37-6
• Molecular Weight: 765.784
• Mol File: 131656-37-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {MnRe(CO)6(η-S2CP(C6H11)3)}(CAS DataBase Reference)
• NIST Chemistry Reference: {MnRe(CO)6(η-S2CP(C6H11)3)}(131656-37-6)
• EPA Substance Registry System: {MnRe(CO)6(η-S2CP(C6H11)3)}(131656-37-6)

Safety Data

• Hazardous Substances Data: 131656-37-6(Hazardous Substances Data)

Upstream product

• 14285-68-8 decacarbonyldirhenium⁽⁰⁾ 
• 33634-75-2 sodium pentacarbonylrhenate 
• 13859-41-1 sodium-manganese pentacarbonyl 

Relevant articles and documents

Selective metal to carbon bond formation in the synthesis of the first rhenium complexes with S2CPCy3 ligands. X-ray structures of [MnRe(CO)6(μ-S2CPCy3)] and [Re2(CO)8(μ-S2CPCy3)]

Reactions of either [Mn(CO)3(S2CPCy3)(Br)] with Na[Re(CO)5] or [Re(CO)3(S2CPCy3)(Br)] with Na-[Mn(CO)5] produce selectively the heterobimetallic complex [MnRe(CO)6(μ-S2CPCy3)], which contains an unsymmetrical η2(S,S′),η3(S,C,S′)-S 2CPCy3 bridge donating eight electrons with the carbon atom of the S2C group bonded to manganese; in contrast, the reaction of [Re-(CO)3(S2CPCy3)(Br)] with Na[Re(CO)5] produces [Re2-(CO)8(μ-S2CPCy3)], with a η1(S),η1(S′)-S2CPCy3 bridge of four electrons and no carbon-rhenium bond. In apparent contradiction with previous theoretical predictions, all the experimental facts suggest a stronger ability for manganese, when compared to rhenium, to become attached to the carbon atom of the S2CPCy3 ligand.