131685-50-2Relevant articles and documents
Assignment of Stereochemistry in the Oligomycin/Rutamycin/Cytovaricin Family of Antibiotics. Asymmetric Synthesis of the Rutamycin Spiroketal Synthon
Evans, David A.,Rieger, Dale L.,Jones, Todd K.,Kaldor, Stephen W.
, p. 6260 - 6268 (2007/10/02)
The absolute stereochemistry of the rutamycin antibiotics 2a,b has been established through asymmetric synthesis of the known degradation product 4.One of the key steps in the assemblage process involves acylation of the metalated hydrazone 6 with the N-m