131722-72-0Relevant academic research and scientific papers
Chiral Induction in Photochemical Reactions, XIII The Paterno-Buechi Reaction of Achiral and Chiral Acyl Cyanides with Furan
Zagar, Cyrill,Scharf, Hans-Dieter
, p. 967 - 969 (2007/10/02)
The acyl cyanides 1a-d are prepared from the corresponding acyl chlorides.The Paterno-Buechi reaction of 1a-f with furan (2) yields the bicyclic oxetanes 3a-f with an endo/exo ratio varying from 3.5:1 (1a) to 16:1 (1d).However, in the reaction of the chiral acyl cyanides 1b and 1c, a low chiral induction is observed (maximum de: 13 percent).
