131722-89-9Relevant academic research and scientific papers
Total, Asymmetric Synthesis of (+)-Castanospermine, (+)-6-Deoxycastanospermine, and (+)-6-Deoxy-6-fluorocastanospermine
Reymond, Jean-Louis,Pinkerton, A. Alan,Vogel, Pierre
, p. 2128 - 2135 (2007/10/02)
Bromination of the dibenzyl acetal of (-)-(1S,4S)-7-oxabicyclohept-5-en-2-one ((-)-5) led to (+)-(1S,5S,6S,7S)-6-endo-(benzyloxy)-5-exo-bromo-7-oxabicycloheptan-2-one (25).Baeyer-Villiger oxidation of 25 gave 2-O-benzyl-3-bromo-3,5-dideoxy-β
A HIGHLY STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)CASTANOSPERMINE
Reymond, Jean-Louis,Vogel, Pierre
, p. 705 - 706 (2007/10/02)
An efficient synthesis of (+/-)castanospermine based on the bromine addition to 7-oxabicyclohept-5-en-2-one benzyl acetal is presented.
