131747-08-5Relevant academic research and scientific papers
Synthesis, photophysical and electrochemical properties of a new class of fluorescent amidoanthracenophanes
Kannan, Ayyavoo,Rajakumar, Perumal
, p. 73951 - 73957 (2015)
Fluorescent amidoanthracenophanes 1, 2, 3 and 4 were obtained from the various aromatic diacid chlorides and diamino precyclophane by simple acylation. All the synthesized amidoanthracenophanes 1, 2, 3 and 4 show three intense fluorescence bands between 401 and 402, 426 and 429, and at 449 to 451 nm, and exhibit two/three oxidation reduction peaks in the cyclic voltammetry which is characteristic of fluorophoric anthracene units.
Transition-state stabilization and molecular recognition: Acceleration of phosphoryl-transfer reactions by an artificial receptor
Tecilla, Paolo,Chang, Suk-Kyu,Hamilton, Andrew D.
, p. 9586 - 9590 (2007/10/02)
An artificial receptor that is complementary to the proposed trigonal-bipyramidal intermediate for phosphoryl-transfer reactions has been designed. Kinetic measurements with 31P NMR methods show that the receptor causes up to a 10-fold acceleration in the aminolysis of phosphorodiamidic chloride derivatives, proceeding via an associative mechanism.
