131755-87-8Relevant articles and documents
An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba12(COO)18(NO3)2 Cluster, for Efficient C3/C2/C1 Separation and Preferential Catalytic Performance
Fan, Weidong,Wang, Yutong,Zhang, Qian,Kirchon, Angelo,Xiao, Zhenyu,Zhang, Liangliang,Dai, Fangna,Wang, Rongming,Sun, Daofeng
, p. 2137 - 2143 (2018)
A barium(II) metal-organic framework (MOF) based on a predesigned amino-functionalized ligand, namely [Ba2(L)(DMF)(H2O)(NO3)1/3]?DMF?EtOH?2 H2O (UPC-33) [H3L=4,4′-((2-amino-5-carboxy-1,3-phenylene)bis(ethyne-2,1-diyl))dibenzoic acid] has been synthesized. UPC-33 is a 3-dimensional 3,18-connected network with fcu topology with a rare twelve-nuclear Ba12(COO)18(NO3)2 cluster. UPC-33 shows permanent porosity and a high adsorption heat of CO2 (49.92 kJ mol?1), which can be used as a platform for selective adsorption of CO2/CH4 (8.09). In addition, UPC-33 exhibits high separation selectivity for C3 light hydrocarbons with respect to CH4 (228.34, 151.40 for C3H6/CH4, C3H8/CH4 at 273k and 1 bar), as shown by single component gas sorption and selectivity calculations. Due to the existence of ?NH2 groups in the channels, UPC-33 can effectively catalyze Knoevenagel condensation reactions with high yield, and substrate size and electron dependency.
An amino-functionalized three-dimensional cadmium metal–organic framework: Synthesis, characterization and excellent fluorescence sensing of Fe3+
Han, Youjie,Tian, Ye,Yin, Jifa,Zhu, Hongmei
, p. 845 - 849 (2021)
An amino-functionalized three-dimensional cadmium metal–organic framework, [Cd1.5(L)(DMF)]·2H2O (complex 1) L = H3TTCA-NH2 = 2′-amino-[1,1′:3′,1″-terphenyl]-4,4″,5′-tricarboxylic acid), is successfully synthesized under solvothermal conditions and structurally characterized. Interestingly, as a transition metal organic framework, the cadmium metal–organic framework exhibits favorable luminescence properties. In addition, the cadmium metal–organic framework reveals excellent selective and sensitive fluorescence sensing for the recognition of Fe3+ with high quenching efficiency (Ksv = 3.340 × 103 M?1), demonstrating that the cadmium metal–organic framework can be used as a potential sensor for Fe3+.
HIGH GLASS TRANSITION TEMPERATURE "MEDIUM-SIZED" AMBIPOLAR HOST MATERIALS
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Page/Page column 35, (2014/02/15)
Disclosed herein are am bipolar host compounds represented by formula (I), wherein: a) R4 is an optionally substituted aryl or an optionally substituted heteroaryl group; b) n is at least 2; e) for each (ii) at least one of R1, R2 and R3 is independently an optionally substituted carbazole group, and the remaining of R1, R2 and R3 are independently selected from hydrogen, halogen and a C1-20 organic group: and d ) Y is selected from (III), wherein R5 is an.optionally substituted aryl group, an optionally substituted heteroaryl group, an optionally substituted alkyl group or an optionally substituted heteroalkyl group, and wherein R6 is hydrogen,, an optionally substituted aryl group, an optionally substituted heteroaryl group, an optionally substituted alkyl -group or an optionally substituted heteroalky! group. The compounds can be used in OLED devices and are ambipolar. The OLED devices can show high efficiency and high luminance.