131766-47-7 Usage
General Description
(SP)-(-)-N-METHYL-N-[(1R,2S)-(2-HYDROXY-1-METHYL-2-PHENYL)ETHYL]AMINO-O-ANIYSYLPHENYLPHOSPHINE is a specific chemical compound that is used in various research and laboratory settings. It is a phosphine compound that contains a phenyl group, an amino group, and a methyl group. (SP)-(-)-N-METHYL-N-[(1R,2S)-(2-HYDROXY-1-METHYL-2-PHENYL)ETHYL]AMINO-O-ANIYSYLPHENYLPHOSPHINE is a chiral molecule, meaning it has non-superimposable mirror images. It is commonly used as a ligand in asymmetric catalysis and has shown potential in the synthesis of pharmaceutical compounds and other organic molecules. Additionally, it has been studied for its potential applications in medicinal chemistry and drug development due to its unique structure and properties.
Check Digit Verification of cas no
The CAS Registry Mumber 131766-47-7 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,1,7,6 and 6 respectively; the second part has 2 digits, 4 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 131766-47:
(8*1)+(7*3)+(6*1)+(5*7)+(4*6)+(3*6)+(2*4)+(1*7)=127
127 % 10 = 7
So 131766-47-7 is a valid CAS Registry Number.
131766-47-7Relevant articles and documents
Study of the bonding properties of the new ligands C5H3N(2-R′)(6-CH2PPhR) toward rhodium(I). Evidence for a dynamic competition for bonding between O- and N-donor centers when R = o-Anisyl, R′ = Me
Yang, Hong,Lugan, No?l,Mathieu, René
, p. 2089 - 2095 (2008/10/08)
The bonding properties of the optically active chiral-at-P polydentate ligands C5H3N(2-R′)(6-CH2PPhR) (R = Me, R′ = H, Me; R = o-anisyl, R′ = H, Me) and the achiral ligand C5H3N(2-Me)(6-CH2PPh2) toward (COD)Rh+ are reported. The results show that steric hindrance of the 2-position of the pyridyl ring induces a labile character of the Rh-N bond. Moreover, for R = o-anisyl and R' = Me, a dynamic competition for bonding between the N-and O-donating centers is observed. Comparison of the solid state structures of complexes [Rh(COD)(C5H4N(2-CH2PPhMe)][BF4] and [Rh(COD)(C5H3N(2-Me)(6-CH2PPh 2)][BF4] shows a significant bond lengthening of the Rh-N bond in the latter complex, consistent with its fluxional behavior observed in solution.
