131771-59-0

Basic information

• Product Name: 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enono-1,5-lactone
• Synonyms: 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enono-1,5-lactone
• CAS NO: 131771-59-0
• Molecular Weight: 324.376
• Mol File: 131771-59-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enono-1,5-lactone(CAS DataBase Reference)
• NIST Chemistry Reference: 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enono-1,5-lactone(131771-59-0)
• EPA Substance Registry System: 4,6-di-O-benzyl-2,3-dideoxy-α-D-erythro-hex-2-enono-1,5-lactone(131771-59-0)

Safety Data

• Hazardous Substances Data: 131771-59-0(Hazardous Substances Data)

Upstream product

• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 64978-34-3 phenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-glucopyranosyl sulfone 
• 38184-10-0 phenyl 2,3,4,5-tetra-O-benzyl-1-thio-β-D-glucopyranoside 
• 64978-35-4 1,5-anhydro-3,4,6-tri-O-benzyl-1,2-dideoxy-1-phenylsulfonyl-D-arabino-hex-1-enitol 

Downstream Products

• 1595290-31-5 C₂₆H₃₀O₃ 
• 1417781-99-7 4,6-di-O-benzyl-2,3-dideoxy-3-diethoxyphosphoryl-D-ribo-hexono-1,5-lactone 
• 1417781-70-4 4,6-di-O-benzyl-2,3-dideoxy-3-diethoxyphosphoryl-D-arabino-hexono-1,5-lactone 
• 236392-24-8 (3S,4S,5R)methyl 5-acetoxy-3-(N,N'-diacetylhydrazino)-4,6-dibenzyloxyhexanoate 
• 236392-23-7 (3S,1'S,2'R)-1,2-diacetyl-5-(2'-acetoxy-1',3'-dibenzyloxypropyl)pyrazolidin-3-one 

Relevant articles and documents

InCl3/IBX: A novel reagent system for the conversion of glycals into α,β-unsaturated δ-lactones

The combination of indium trichloride with iodoxybenzoic acid (IBX) has been utilized for the first time as a novel reagent system for the one-pot synthesis of 2,3-dideoxy-D-hex-2-enono-1,5-lactones from glycals. The reaction proceeds smoothly in aqueous

Synthesis of C-spiro-glycoconjugates from sugar lactones via zinc mediated Barbier reaction

Anomeric gem-diallylation, mono-β-crotylation and mono-β- propargylation of sugar 1,5 and 1,4 lactones have been achieved under Barbier reaction conditions using Zn powder and a catalytic amount of TMSCl as an activator. Ring closing olefin metathesis of the synthesized gem-diallyl derivatives furnished C-spiro cyclopentene glycosides. Finally, the cyclopentene rings were converted into carbohydrate based tricyclic morpholine fused triazole glycoconjugates as potential SGLT2 inhibitors.