131779-79-8

Basic information

• Product Name: CIS-2-(3,4-METHYLENEDIOXYBENZOYL)CYCLOHEXANE-1-CARBOXYLIC ACID
• Synonyms: CIS-2-(3,4-METHYLENEDIOXYBENZOYL)CYCLOHEXANE-1-CARBOXYLIC ACID
• CAS NO: 131779-79-8
• Molecular Formula: C₁₅H₁₆O₅
• Molecular Weight: 276.28
• Mol File: 131779-79-8.mol
• Article Data: 3

Chemical Properties

• Melting Point: 152-154 °C
• Boiling Point: 494.8±45.0 °C(Predicted)
• Appearance: /
• Density: 1.335±0.06 g/cm3(Predicted)
• PKA: 4.48±0.44(Predicted)
• CAS DataBase Reference: CIS-2-(3,4-METHYLENEDIOXYBENZOYL)CYCLOHEXANE-1-CARBOXYLIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: CIS-2-(3,4-METHYLENEDIOXYBENZOYL)CYCLOHEXANE-1-CARBOXYLIC ACID(131779-79-8)
• EPA Substance Registry System: CIS-2-(3,4-METHYLENEDIOXYBENZOYL)CYCLOHEXANE-1-CARBOXYLIC ACID(131779-79-8)

Safety Data

• Hazardous Substances Data: 131779-79-8(Hazardous Substances Data)

Upstream product

• 109586-40-5 1,3-dihydroisobenzofuran-5-yl trifluoromethanesulfonate 
• 13149-00-3 1,2-cis-cyclohexanedicarboxylic anhydride 
• 2635-13-4 1,2-(methylenedioxy)-4-bromobenzene 

Downstream Products

• 131779-88-9 C₂₅H₂₉NO₆S 
• 131779-83-4 N-[(1R,2S)-2-(Benzo[1,3]dioxole-5-carbonyl)-cyclohexyl]-4-methyl-benzenesulfonamide 
• 131779-80-1 N-[(1R,2R)-2-(1-Benzo[1,3]dioxol-5-yl-vinyl)-cyclohexyl]-4-methyl-benzenesulfonamide 
• 131779-81-2 [(1R,2R)-2-(1-Benzo[1,3]dioxol-5-yl-vinyl)-cyclohexyl]-carbamic acid tert-butyl ester 
• 131779-87-8 N-[(1S,2S)-2-(1-Benzo[1,3]dioxol-5-yl-vinyl)-cyclohexyl]-methanesulfonamide 
• 129483-43-8 N-[(1R,2R)-2-((S)-1-Benzo[1,3]dioxol-5-yl-2-hydroxy-ethyl)-cyclohexyl]-4-methyl-benzenesulfonamide 
• 131779-82-3 [(1R,2S)-2-(Benzo[1,3]dioxole-5-carbonyl)-cyclohexyl]-carbamic acid tert-butyl ester 

Relevant articles and documents

Nickel-Catalyzed Desymmetrizing Cross-Electrophile Coupling of Cyclic Meso-Anhydrides

A Ni-catalyzed desymmetrizing cross-electrophile coupling of cyclic meso-anhydrides with aryl triflates has been successfully demonstrated. This is the only example using cyclic meso-anhydrides in cross-electrophile coupling reactions. A diverse array of valuable γ-keto acid building blocks can be generated under these conditions with excellent functional group tolerance and stereochemical fidelity.

A Stereoselective Synthesis of a Basic Skeleton of Amaryllidaceae Montanine-type Alkaloids, (+/-)-4a,11a-cis-11,11a-syn-5,11-Methanomorphanthridine Ring System

A title compound was synthesized by reductive cyclization of 4a,11a-cis-11,11a-syn-11-acetoxymethyl-N-p-tosylmorphanthridine or N-detosylated alcohol derived from a hydroxymethyl-p-tosylamide prepared by hydroboration-oxidation of cis-1-(p-tosylamido)-2-v