131780-95-5Relevant academic research and scientific papers
A dual site catalyst for mild, selective nitrile reduction
Lu, Zhiyao,Williams, Travis J.
, p. 5391 - 5393 (2014)
We report a novel ruthenium bis(pyrazolyl)borate scaffold that enables cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect selective nitrile reduction. The pre-catalyst compound [κ3-(1-pz)2HB(N = CHCH3)]Ru(cymene) + TfO- (pz = pyrazolyl) was synthesized using readily-available materials through a straightforward route, thus making it an appealing catalyst for a number of reactions. the Partner Organisations 2014.
DUAL SITE CATALYST FOR MILD, SELECTIVE NITRILE REDUCTION
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Paragraph 0052, (2016/06/09)
A ruthenium bis(pyrazolyl)borate scaffold that enables cooperative reduction reactivity in which boron and ruthenium centers work in concert to effect selective nitrile reduction is provided. The pre-catalyst compound [κ3-(1-pz)2HB(N═CHCH3)]Ru(cymene)? TfO? (pz=pyrazolyl) was synthesized using readily-available materials through a straightforward route, thus making it an appealing catalyst for a number of reactions.
