131784-69-5

Basic information

• Product Name: Carbamic acid, (3-methyl-1,3-butadienyl)-, 1,1-dimethylethyl ester, (E)- (9CI)
• Synonyms: Carbamic acid, (3-methyl-1,3-butadienyl)-, 1,1-dimethylethyl ester, (E)- (9CI)
• CAS NO: 131784-69-5
• Molecular Formula: C₁₀H₁₇NO₂
• Molecular Weight: 183.24748
• Product Categories: N-BOC
• Mol File: 131784-69-5.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Carbamic acid, (3-methyl-1,3-butadienyl)-, 1,1-dimethylethyl ester, (E)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (3-methyl-1,3-butadienyl)-, 1,1-dimethylethyl ester, (E)- (9CI)(131784-69-5)
• EPA Substance Registry System: Carbamic acid, (3-methyl-1,3-butadienyl)-, 1,1-dimethylethyl ester, (E)- (9CI)(131784-69-5)

Safety Data

• Hazardous Substances Data: 131784-69-5(Hazardous Substances Data)

Upstream product

• 107-86-8 3,3-dimethyl acrylaldehyde 
• 4248-19-5 tert-butyl carbazate 

Downstream Products

• 141966-85-0 tert-butyl (3-methyl-6-carbomethoxy-2-cyclohexen-1-yl)-carbamate 

Relevant articles and documents

Catalytic Asymmetric Diels-Alder Reaction of Quinone Imine Ketals: A Site-Divergent Approach

The catalytic asymmetric Diels-Alder reaction of quinone imine ketals with diene carbamates catalyzed by axially chiral dicarboxylic acids is reported herein. A variety of primary and secondary alkyl-substituted quinone derivatives which have not been applied in previous asymmetric quinone Diels-Alder reactions could be employed using this method. More importantly, we succeeded in developing a strategy to divert the reaction site in unsymmetrical 3-alkyl quinone imine ketals from the inherently favored unsubstituted C=C bond to the disfavored alkyl-substituted C=C bond.