131802-29-4Relevant academic research and scientific papers
Palladium-catalyzed carbonylative synthesis of acylstannanes from aryl iodides and hexamethyldistannane
Chen, Bo,Franke, Robert,Wu, Xiao-Feng,Xu, Jian-Xing,Yuan, Yang
supporting information, (2020/07/21)
In this communication, we describe a new method for the carbonylative synthesis of acylstannanes from aryl iodides and hexamethyldistannane. With Pd(PPh3)4 as the catalyst and toluene as the solvent at 60 °C under 10 bar CO for 16 h, the desired acylstannanes were obtained in good to excellent yields. In order to facilitate isolation and analysis, the obtained acylstannanes were transformed into the corresponding benzoic acids by simply stirring under air for 5 h.
Some further studies on acyltrimethylstannanes
Mitchell, Terence N.,Kwetkat, Klaus
, p. 127 - 138 (2007/10/02)
The scope and limitations of the palladium-catalysed preparation of acyltins from ditins and acyl chlorides are discussed in detail.Preliminary studies on the chemistry of acyltrimethylstannanes are described.
