1318238-88-8

Basic information

• Product Name: [Pd(bis(4-methylthiazolyl)isoindoline(-1H))(dimethylselenide)] tetrakis(3,5-bis(trifluoromethyl)phenyl)boranate
• CAS NO: 1318238-88-8
• Molecular Weight: 1417.11
• Mol File: 1318238-88-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Pd(bis(4-methylthiazolyl)isoindoline(-1H))(dimethylselenide)] tetrakis(3,5-bis(trifluoromethyl)phenyl)boranate(CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(bis(4-methylthiazolyl)isoindoline(-1H))(dimethylselenide)] tetrakis(3,5-bis(trifluoromethyl)phenyl)boranate(1318238-88-8)
• EPA Substance Registry System: [Pd(bis(4-methylthiazolyl)isoindoline(-1H))(dimethylselenide)] tetrakis(3,5-bis(trifluoromethyl)phenyl)boranate(1318238-88-8)

Safety Data

• Hazardous Substances Data: 1318238-88-8(Hazardous Substances Data)

Upstream product

• 593-79-3 dimethylselenide 
• 1107012-49-6 chlorido[bis(4-methylthiazolyl)isoindoline]palladium(II) 
• 79060-88-1 sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate 

Relevant articles and documents

Cationic palladium(II) complexes of the sterically hindered bis(4-methylthiazolyl)isoindoline (4-Mebti) with neutral group XVI donor ligands

A series of cationic palladium complexes [(4-Mebti)PdL]+ with 4-Mebti = anion of bis(4-methylthiazolylimino)isoindoline and L = neutral ligand with group 16 donor atom has been prepared from the chlorido derivative [(4-Mebti)PdCl] and NaBArF (BArF = tetrakis(3,5- bis(trifluoromethyl)phenyl)boranate) in the presence of the respective donor ligand. Crystallographic and spectroscopic analyses were achieved for species with L = SMe2, SeMe2, dmf, acetamide, diphenylurea, and formiate. The latter two complexes represent products from hydrolyses of phenyl isocyanate and dmf, respectively, which occur during the ligand exchange reactions. Several other O-donor ligands like thf, acetone, Me2O, water, and others are not bound to the palladium ion, and the dinuclear μ-chlorido derivative [{(4-Mebti)Pd}2Cl]+ is isolated in these cases instead. The crystallographic analyses prove the expected presence of distorted, pseudo-planar palladium chelates, and the degree of distortion correlates well with the chemical shifts observed for the proton nuclei of the terminal methyl groups in the 1H NMR experiment.