131833-65-3Relevant academic research and scientific papers
A Comparsion between Zeolite-Solvent Slurry and Dry Solid Photolyses
Ramamurthy, V.,Corbin, D. R.,Turro, N. J.,Zhang, Z.,Garcia-Garibay, M. A.
, p. 255 - 261 (1991)
The use of zeolite-solvent slurry as a convenient medium to carry out photoreactions is illustrated with four examples, namely Norrish type I reaction of dibenzyl ketones, Norrish type I and type II reactions of α-alkylbenzyl benzyl ketones, Norrish type II reaction of aryl alkyl ketones, and photodimerization of acenaphthylene.Solvent present within the supercages of zeolites X and Y provides constraint on the mobility of the included guest molecules.Such restrictions are reflected in the product distributions.The difference in the product distribution obtained between the zeolite-solvent slurry and a homogeneous solution is often higher than that between the dry powder zeolites and a homogeneous solution.
