131883-99-3Relevant academic research and scientific papers
The conversion of olefins to β-keto esters: Ozonolysis of olefins followed by in situ reduction with tin(II) chloride in the presence of ethyl diazoacetate
Holmquist, Christopher R.,Roskamp, Eric J.
, p. 4991 - 4994 (1990)
Trisubstituted olefins are converted to β-keto esters by treatment with ozone followed by the addition of tin(H) chloride and ethyl diazoacetate. Monosubstituted olefins are first treated with ozone in the presence of methanol to generate methoxy hydroperoxides. The hydroperoxides are subsequently reduced with tin(II) chloride in the presence of ethyl diazoacetate to produce β-keto esters.
