1318897-74-3Relevant academic research and scientific papers
Diastereoselective and highly enantioselective henry reactions using C 1-symmetrical copper(II) complexes
Chougnet, Antoinette,Zhang, Guoqi,Liu, Kegang,Haeussinger, Daniel,Kaegi, Andreas,Allmendinger, Thomas,Woggon, Wolf-D.
experimental part, p. 1797 - 1806 (2011/09/13)
Catalytic Henry reactions of aliphatic aldehydes and prochiral nitro compounds were investigated using copper(II) complexes of 14 C 1-symmetrical ligands derived from (1R,2R)(-)-diaminocyclohexane. β-Nitro alcohols with syn:anti ratios of up to 5.7 and excellent ee values for both diastereosimers were obtained. Copyright
