131929-20-9Relevant academic research and scientific papers
N,N'-DIARYLDICHLOROMALONIMIDOYL CHLORIDES AND THEIR TRANSFORMATIONS
Shivanyuk, A. F.,Dashkovskaya, E. V.,Rozhenko, A. B.,Lozinskii, M. O.,Onishchuk, N. P.,et al.
, p. 1408 - 1416 (2007/10/02)
The hydrolysis and alcoholysis of N,N'-diaryldichloromalonimidoyl chlorides and their reactions with sodium azide in DMFA, with hydrazine hydrate and with triphenylphosphine lead to N,N'-diaryldichloromalonamides, imidic esters, bis(1-aryl-1,2,3,4-tetrazol-5-yl)iminomethanes, 3,5-diarylamino-4-chloropyrazoles, and 4-arylamino-3-chloro-2-quinolyltriphenylphosphomium chlorides.Depending on the nature of the nucleophilic agent, the N,N'-diaryldichloromalonimidoyl chlorides react either at the imidoyl chloride group N=C(Cl) (hydrolysis, alcoholysis) or at the two reactioncenters N=C(Cl)CCl2 (the reactions with hydrazine hydrate and triphenylphosphine).
