1319746-92-3Relevant academic research and scientific papers
A new 3D metal-organic framework with (4, 8)-connected AlB2 topology constructed from coordinated evolution of a C3 symmetry ligand
Ma, Running,Chen, Chao,Sun, Bin,Zhao, Xiaoting,Zhang, Ning
, p. 1532 - 1536 (2011)
A new 3D lanthanide metal-organic framework, {[Ce(L)(DMF)]?2.5(DMF) ?3(H2O)}n (1) (H3L = N,N′,N″- tris(4-carboxyphenyl)-1,3,5-benzenetricarboxamide, DMF = N,N′- dimethylformamide) has been synthesized under solvothermal condition. Compound 1 features a 3D non-interpenetrated binodal (4, 8)-connected AlB2 topology with a Schlaefli symbol of (45.6)2(4 10.614.84), where the C3 symmetry ligand H3L evolves into an unusual 4-connected node and dinuclear cerium cluster acts as an 8-connected node. Furthermore, compound 1 displays blue emission in the solid state at room temperature.
