131980-62-6Relevant articles and documents
Fused 1,2,3-dithiazoles: Convenient synthesis, structural characterization, and electrochemical properties
Konstantinova, Lidia S.,Baranovsky, Ilia V.,Irtegova, Irina G.,Bagryanskaya, Irina Y.,Shundrin, Leonid A.,Zibarev, Andrey V.,Rakitin, Oleg A.
, (2016)
A new general protocol for synthesis of fused 1,2,3-dithiazoles by the reaction of cyclic oximes with S2Cl2 and pyridine in acetonitrile has been developed. The target 1,2,3-dithiazoles fused with various carbocycles, such as indene,
Cyclopenta-1,2,3-dithiazoles and Related Compounds
Plater, M. John,Rees, Charles W.,David, G. Roe,Torroba, Tomas
, p. 769 - 774 (2007/10/02)
Treatment of 3-phenylinden-1-one oxime 6 with disulfur dichloride gives the indenodithiazole 2 directly in 58percent; in the presence of Huenig's base the yield rises to 90percent.Indenone oxime 9 and indanone oxime 11 with disulfur dichloride both give t
Pyrazolotrithiadiazepines and their Unexpected Rearrangement to 1,2,3-Dithiazoles
Plater, M. John,Rees, Charles W.
, p. 1319 - 1320 (2007/10/02)
Treatment of 6-bromotrithiadiazepine (1) with Huenig's base in the presence of diaryldiazomethanes (2) gives the trithiadiazepyne cycloadducts (3) which undergo a deep-seated thermal rearrangement to give fused 1,2,3-dithiazoles (4), for which a mechanism