131981-97-0Relevant academic research and scientific papers
Synthesis and Asymmetric Diels-Alder Reactions of Enantiopure 3-(Alkylsulfinyl)-1-methoxy-1,3-butadienes
Aversa, Maria C.,Barattucci, Anna,Bonaccorsi, Paola,Giannetto, Placido,Jones, David Neville
, p. 4376 - 4384 (2007/10/03)
Simple syntheses of enantiopure (E)- and (Z)-3-(alkylsulfinyl)-1-methoxy-1,3-butadienes 2 and 3 were provided by the addition of (1S)-isoborneol-10-sulfenic and (S)-phenyl-2-hydroxyethanesulfenic acids 8 to (E)- and (Z)-1-methoxybut-1-en-3-ynes (9) and (1
Asymmetric Diels-Alder reactions of enantiopure 1-methoxy-3-(phenyl-2- hydroxyethylsulfinyl)-1,3-butadienes
Aversa,Bonaccorsi,Giannetto,Jones
, p. 805 - 808 (2007/10/02)
Enantiopure 1-methoxy-3-(1-phenyl- and 2-phenyl-2-hydroxyethylsulfinyl)- 1,3-butadienes were prepared from ethyl mandelate. Diels-Alder reactions with methyl acrylate proceeded with complete regioselectivity and high diastereoselectivity.
