1320281-35-3

Upstream product

• 1320281-41-1 1,4,6-tri-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α/β-D-mannopyranoside 
• 106-45-6 para-thiocresol 

Downstream Products

• 1320281-36-4 p-tolyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-1-thio-α-D-mannopyranoside 
• 1320281-42-2 p-tolyl 2-azido-3-O-benzyl-2-deoxy-1-thio-α-D-mannopyranoside 
• 1320281-72-8 methyl (p-tolyl 4-O-acetyl-2-azido-3-O-benzyl-2-deoxy-1-thio-α-D-mannopyranosyluronate) 
• 1320281-44-4 C₂₁H₂₃N₃O₅S 

Relevant academic research and scientific papers

Mannopyranosyl uronicaAcid donor reactivity

The reactivity of a variety of mannopyranosyl uronic acid donors was assessed in a set of competition experiments, in which two (S)-tolyl mannosyl donors were made to compete for a limited amount of promoter (NIS/TfOH). These experiments revealed that the reactivity of mannuronic acid donors is significantly higher than expected based on the electron-withdrawing capacity of the C-5 carboxylic acid ester function. A 4-O-acetyl-β-(S)-tolyl mannuronic acid donor was found to have similar reactivity as per-O-benzyl-α-(S)-tolyl mannose.