132054-98-9Relevant academic research and scientific papers
Role of chiral auxiliaries in the type 2 intramolecular Diels-Alder reaction. Influence on diastereoselectivity
Shea, Kenneth J.,Gauthier Jr., Donald R.
, p. 7311 - 7314 (1994)
The incorporation of a chiral auxiliary as part of a disposable tether in the type 2 intramolecular Diels-Alder cycloaddition leads to a pair of diastereomers. Separation of the diastereomers and tether removal yields enantiomerically pure cyclohexanes and decalins.
Disposable tethers in type 2 intramolecular Diels-Alder cycloaddition reactions. Applications in stereochemical control
Shea,Zandi,Staab,Carr
, p. 5885 - 5888 (2007/10/02)
Temporary union of diene and dienophile in the type 2 intramolecular Diels-Alder cycloaddition provides a general strategy for controlling both regio- and stereochemistry of the cycloaddition.
