132069-08-0

Basic information

• Product Name: [bis(2,9-diphenyl-1,10-phenanthroline)copper(I)]dichlorocuprate
• CAS NO: 132069-08-0
• Molecular Weight: 862.807
• Mol File: 132069-08-0.mol

Chemical Properties

• CAS DataBase Reference: [bis(2,9-diphenyl-1,10-phenanthroline)copper(I)]dichlorocuprate(CAS DataBase Reference)
• NIST Chemistry Reference: [bis(2,9-diphenyl-1,10-phenanthroline)copper(I)]dichlorocuprate(132069-08-0)
• EPA Substance Registry System: [bis(2,9-diphenyl-1,10-phenanthroline)copper(I)]dichlorocuprate(132069-08-0)

Safety Data

• Hazardous Substances Data: 132069-08-0(Hazardous Substances Data)

Upstream product

• 25677-69-4 2,9-diphenyl-1,10-phenanthroline 

Relevant articles and documents

Synthesis, structure, and spectroscopic and electrochemical properties of copper(II/I) Complexes with symmetrical and unsymmetrical 2, 9-Diaryl-1,10-phenanthroline ligands

A series of copper(II) and copper(I) complexes, [CuX2L] (16) and [CuL2](CuX2) (7-12) (X = Cl, Br; L = 2-R-9-R′-l, 10phenanthroline, dpp: R = R′ = Ph; npp: R = naphthyl, R′ = Ph; dnp: R = R′ = naphthyl) were synthesized and characterized by elemental analysis, UV/Vis and IR spectroscopy, and Xray crystal diffraction (for 1, 3, 6, and 12), The copper(II) complexes are four-coordinate with one phenanthroline ligand and two halogen atoms, whereas the copper(I) complexes are tetrahedrally coordinated by two bidentate phenanthroline ligands. Cyclic voltammetry studies of the CuI complexes in CH2Cl2 reveal that bulky groups in the 2,9-positions have significant effects on the redox potential of the CuII/I couple, which is more positive for the complexes with the dnp ligand than those with the dpp and npp ligands,