132091-65-7

Basic information

• Product Name: 2-heneicosafluorodecylcyclohexanone
• Synonyms: 2-heneicosafluorodecylcyclohexanone
• CAS NO: 132091-65-7
• Molecular Weight: 616.213
• Mol File: 132091-65-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-heneicosafluorodecylcyclohexanone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-heneicosafluorodecylcyclohexanone(132091-65-7)
• EPA Substance Registry System: 2-heneicosafluorodecylcyclohexanone(132091-65-7)

Safety Data

• Hazardous Substances Data: 132091-65-7(Hazardous Substances Data)

Upstream product

• 423-62-1 1-Iodo-perfluorodecane 
• 6651-36-1 1-(Trimethylsilyloxy)cyclohexene 
• 930-68-7 cyclohexenone 
• 132091-60-2 C₁₅H₃₀GeO 

Relevant articles and documents

α-Fluoroalkylation of carbonyl compounds mediated by a highly reactive alkyl-rhodium complex

Treatment of silyl enol ethers of various carbonyl compounds with Et2Zn and fluoroalkyl halides (Rf-X) in the presence of RhCl(PPh3)3 in DME gave the corresponding α-Rf carbonyl compounds. A highly reactive alkyl-rhodium complex which was derived from RhCl(PPh3)3 and Et2Zn must be crucial in this reaction by accelerating the reaction rate and improving the yields dramatically. This reaction overcomes difficulties on the synthesis of α-Rf carbonyl compounds due to inverse polarization of Rf-X.

TRIETHYLBORANE INDUCED PERFLUOROALKYLATION OF SILYL ENOL ETHERS OR GERMYL ENOL ETHERS WITH PERFLUOROALKYL IODIDES

Reaction of perfluoralkyl iodides with silyl enol ethers mediated by Et3B in the presence of a base provides perfluoroalkylated silyl enol ethers.Meanwhile, treatment of germyl enol ethers with perfluoroalkyl iodides affords α-perfluoroalkyl ketones in good yields.