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Reactions of 5H-1,2λ5-Azaphospholes with Arylazocarbonitriles and Dialkyl Acetylenedicarboxylates
Ried, Walter,Fulde, Maria,Bats, Jan W.
, p. 1888 - 1893 (2007/10/02)
Azaphosholes 1a-c react with activated arylazocarbonitriles to 1,5,2λ5-diazaphosphorines 2a-c and 3a-c.The reaction of 1a-c with diethyl or dimethyl acetylenedicarboxylates yields 7H-1,4λ5-azaphosphepines 4a-c.The structures of 2b, 3a, and 4a are established by an X-ray diffraction analysis.
