132151-93-0Relevant academic research and scientific papers
MODEL STUDIES DIRECTED TOWARD MICROALGA POLYETHER MACROLIDES: A ROUTE TO OXYGENATED 2,5-CIS TETRAHYDROFURAN SUBUNITS
Alvarez, Eleuterio,Zurita, Dacil,Ruiz-Perez, Catalina,Rodriguez, Matias L.,Martin, Julio D.
, p. 3729 - 3732 (1989)
The regio- and stereochemistry of iodine-promoted transannular ring expansion of a cyclic trans-1,2-epoxy-4(E)-ene system is used to synthesize a cis-α,α'-dialkylated tetrahydrofuran subunit.
MODEL STUDIES DIRECTED TOWARDS MICROALGA POLYETHER TOXINS
Alvarez, Eleuterio,Diaz, Maria Teresa,Zurita, Dacil,Zarraga, Miguel,Martin, Julio D.
, p. 635 - 645 (2007/10/02)
In view of the described results in acid-induced polyepoxide cyclizations, the biosynthesis of fused polyether toxins may be better explained by a stepwise mechanism through oxonium ion intermediates acting on the enzyme-bonded polyepoxide precursor.A new
