1321591-83-6

Basic information

• Product Name: (E)-tert-butyl (3-(4-methoxyphenyl)-1-phenylallyl)carbamate
• Synonyms: (E)-tert-butyl (3-(4-methoxyphenyl)-1-phenylallyl)carbamate
• CAS NO: 1321591-83-6
• Molecular Weight: 339.434
• Mol File: 1321591-83-6.mol

Chemical Properties

• CAS DataBase Reference: (E)-tert-butyl (3-(4-methoxyphenyl)-1-phenylallyl)carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-tert-butyl (3-(4-methoxyphenyl)-1-phenylallyl)carbamate(1321591-83-6)
• EPA Substance Registry System: (E)-tert-butyl (3-(4-methoxyphenyl)-1-phenylallyl)carbamate(1321591-83-6)

Safety Data

• Hazardous Substances Data: 1321591-83-6(Hazardous Substances Data)

Upstream product

• 201852-49-5 potassium (E)-trifluoro(styryl)borate 
• 479423-40-0 N-tert-butyl 4-methoxybenzylidenecarbamate 
• 24424-99-5 di-tert-butyl dicarbonate 
• 39212-13-0 (E)-1-phenyl-3-(4-methoxyphenyl)prop-2-en-1-ol 
• 4248-19-5 tert-butyl carbazate 

Relevant articles and documents

The acid promoted Petasis reaction of organotrifluoroborates with imines and enamines

The acid promoted addition of organotrifluoroborate salts to imine and enamine electrophiles is reported. Use of the pre-activated trifluoroboronate complex bypasses the need for α-hetero substitution on the electrophile component, greatly expanding the scope of the Petasis borono-Mannich reaction. A variety of vinyl, aromatic and heteroaromatic trifluoroborate salts undergo addition with good efficiency under mild reaction conditions. The reaction is amenable for use with a variety of carbamate protected imine and enamine electrophiles, achieving for the first time the effective coupling with aliphatic aldehydes.

Platinum-catalyzed direct amination of allylic alcohols with aqueous ammonia: Selective synthesis of primary allylamines

Direct amination of unactivated allylic alcohols with aqueous ammonia was catalyzed by a Pt/phosphine complex to give the corresponding allylamines along with water as the sole by-product. Under optimized reaction conditions, primary allylamines were obtained as major products with excellent monoallylation selectivity. cod=1,5-cyclooctadiene.

Direct substitution of the hydroxy group with highly functionalized nitrogen nucleophiles catalyzed by Au(III)

A direct catalytic substitution of various allylic and benzylic alcohols with synthetically useful, but acid-sensitive Boc, Bus, and Dios protected amine nucleophiles, which have not been well utilized for Lewis acid catalysis, with various functionalities (OTBS, OTHP, etc.) was efficiently catalyzed by 1 mol% of Au(iii) under mild conditions.