132196-96-4

Basic information

• Product Name: 5-isopropenyl-2-methyl-3-oxocyclohexanecarbonitrile
• Synonyms: 5-isopropenyl-2-methyl-3-oxocyclohexanecarbonitrile
• CAS NO: 132196-96-4
• Molecular Formula: C₁₁H₁₅NO
• Molecular Weight: 177.2429
• Mol File: 132196-96-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-isopropenyl-2-methyl-3-oxocyclohexanecarbonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: 5-isopropenyl-2-methyl-3-oxocyclohexanecarbonitrile(132196-96-4)
• EPA Substance Registry System: 5-isopropenyl-2-methyl-3-oxocyclohexanecarbonitrile(132196-96-4)

Safety Data

• Hazardous Substances Data: 132196-96-4(Hazardous Substances Data)

Upstream product

• 332920-11-3 (5R)-5-isopropenyl-2-methyl-1-trimethyl-silanyloxy-cyclohex-2-ene-1-carbonitrile 
• 6485-40-1 (R)-Carvone 
• 99-48-9 (4R,6R)-carveol 
• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 151-50-8 potassium cyanide 

Downstream Products

• 2244-16-8 (S)-p-mentha-6,8-dien-2-one 
• 1212223-60-3 5-isopropenyl-2-methyl-3-oxo-cyclohexanecarboxylic acid amide 

Relevant articles and documents

Dauben-Michno oxidative transposition of allylic cyanohydrins - Enantiomeric switch of (-)-carvone to (+)-carvone

Allylic cyanohydrins were subjected to Dauben-Michno oxidation at low temperatures to provide β-cyanoenones in good to excellent yields. The potential of this oxidative transposition as a means of an enantiomeric switch of enones containing a latent plane of symmetry was tested by conversion of (-)-carvone to its enantiomer.