1322076-08-3Relevant academic research and scientific papers
Unexpected diastereoselective one-pot assembly of hexahydroazulenones from 2-alkylcyclohexanones and arylacetylenes in KOH/DMSO suspension
Trofimov, Boris A.,Schmidt, Elena Yu.,Skitaltseva, Elena V.,Zorina, Nadezhda V.,Protsuk, Nadezhda I.,Ushakov, Igor A.,Mikhaleva, Albina I.,Dyachenko, Oleg A.,Kazheva, Olga N.,Aleksandrov, Grigorii G.
, p. 4285 - 4287 (2011)
2-Alkylcyclohexanones react with arylacetylenes (KOH/DMSO, 100 °C, 1 h) to afford unexpectedly hexahydroazulenones in 34-50% yields and ca. 100% diastereoselectivity (instead of the expected acetylenic alcohols), the minor products being isomeric arylethe
