132250-16-9Relevant academic research and scientific papers
Facile Synthesis of the Matallacyclic Rings , and ; Crystal Structures of and
Kemmitt, Raymond D. W.,Mason, Simon,Moore, Mark R.,Fawcett, John,Russell, David R.
, p. 1535 - 1537 (2007/10/02)
Reaction of PhCOCH2P(O)(Ph)CH2COPh, RNHP(O)(Ph)NHR or RNHS(O)2NHR (R = H or Ph) with cis- (L = PPh3 or PMePh2; L2 = Ph2PCH2CH2PPh2 or cycloocta-1,5-diene) in the presence of silver(I) oxide gives metallacyclic complexes of the type , or respectively; single crystal X-ray studies on and the insertion product establish the presence of puckered metallacycles, the oxygen of the platinaphosphetane-3-oxide adopting an equatorial environment.
