132277-33-9

Basic information

• Product Name: 2-(3-Methylbut-2-enyloxy)phenol
• Synonyms: 2-(3-methylbut-2-enyloxy)phenol;2-[(3-Methyl-2-butenyl)oxy]phenol
• CAS NO: 132277-33-9
• Molecular Formula: C₁₁H₁₄O₂
• Molecular Weight: 178.23
• Mol File: 132277-33-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 282 °C
• Flash Point: 127 °C
• Appearance: /
• Density: 1.040
• Refractive Index: 1.533
• CAS DataBase Reference: 2-(3-Methylbut-2-enyloxy)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-Methylbut-2-enyloxy)phenol(132277-33-9)
• EPA Substance Registry System: 2-(3-Methylbut-2-enyloxy)phenol(132277-33-9)

Safety Data

• Hazardous Substances Data: 132277-33-9(Hazardous Substances Data)

Usage

Physical state

clear, colorless to pale yellow liquid

Odor

characteristic floral and spicy

Usage in fragrance industry

sweet, clove-like scent

Usage as flavoring agent

food industry

Properties

antiseptic and antibacterial

Common applications

dental products and soaps

Skin sensitivity

can cause allergic reactions in some individuals

Safety precautions

handle and use with proper care

InChI:InChI=1/C11H14O2/c1-9(2)7-8-13-11-6-4-3-5-10(11)12/h3-7,12H,8H2,1-2H3

Upstream product

• 120-80-9 benzene-1,2-diol 
• 870-63-3 prenyl bromide 

Downstream Products

• 1430847-85-0 1-{2-(4-chlorophenyl)-4-[2-(3-methyl-but-2-enyloxy)phenoxymethyl]-[1,3]-dioxolan-2-ylmethyl}-1H-[1,2,4]-triazole 
• 132277-36-2 (+/-)-3,4-dihydro-2,2-dimethyl-3-(phenylseleno)-2H-benzodioxepin 
• 172226-17-4 (+/-)-2-<(3,3-dimethyloxiranyl)methoxy>phenol 

Relevant articles and documents

Investigation of the New Zealand basidiomycete Favolaschia calocera: Revision of the structures of 9-methoxystrobilurins L and L, strobilurin D, and hydroxystrobilurin D

9-Methoxystrobilurin K has been obtained from Favolaschia calocera. The previously proposed epoxyprenyl structure for 9-methoxystrobilurin K 2c and dioxan structure for 9-methoxystrobilurin L 3 have both been revised to the prenyldioxepin structure 1a. The epoxyprenyl structures of strobilurin D 2a and hydroxystrobilurin D 2c should also be revised.

SYNTHETIC STUDIES ON PARAHERQUAMIDE: SYNTHESIS OF THE 2H-1,5-BENZODIOXEPIN RING SYSTEM

Various 2H-2,2-dimethyl-1,5-benzodioxepins have been synthesized en route to the oxindole moiety of paraherquamide (1).The key step is the 7-membered ring formation from prenylated catechols using either PhSeCl, N-PSP or m-CPBA/SnCl4.