132282-39-4Relevant academic research and scientific papers
Synthetic applications of the [2+2] cycloaddition products of ketene alkylsilylacetals with acrylonitrile
Rousseau,Quendo
, p. 6361 - 6370 (2007/10/02)
2-Cyanocyclobutane alkylsilylacetals, obtained by a [2+2] cycloaddition reaction of ketene alkylsilylacetals and acrylonitrile, have allowed the synthesis of 2-cyanoclobutanones, 4-chloro-4-cyanobutanoates and 4-cyanobutanoates by respectively acidic cata
Reaction of ketene silyl acetals with unsaturated nitrites in the presence of titanium tetrachloride
Ali, Syed Masarrat,Rousseau, Gerard
, p. 7011 - 7018 (2007/10/02)
The reaction of ketene alkyl silyl acetals with acrylonitrile in the presence of titanium tetrachloride in dichloromethane at -80°C leads to coupled compounds. Formation of these products can be explained by the transformation of ketene acetals into enoxy
REACTION OF KETENEALKYLSILYLACETALS WITH ACRYLONITRILE AND 2-CHLOROACRYLONITRILE
Quendo, A.,Rousseau, G.
, p. 1551 - 1560 (2007/10/02)
The Lewis acid catalyzed reaction of ketenealkylsilylacetals with acrylonitrile and 2-chloroacrylonitrile can take place via two pathways: a cycloaddition in CCl4-ZnBr2 and a Michaoel-type addition in CH2Cl2-ZnI2.
