132304-73-5Relevant academic research and scientific papers
TaMe3Cl2-catalyzed intermolecular hydroaminoalkylation: A simple complex for enhanced reactivity and expanded substrate scope
Zhang, Zhengxing,Hamel, Jean-Denys,Schafer, Laurel L.
supporting information, p. 8751 - 8754 (2013/07/26)
Tantalizingly simple: The common organometallic starting material TaMe 3Cl2 can be used for the catalytic C-H functionalization reaction, hydroaminoalkylation. The substrate scope for this readily accessed compound includes unactivat
154. Reduction of Indolin-2-ones and Desulfurization of Indoline-2-thiones to Indoline and Indole Derivatives
Nishio, Takehiko,Okuda, Norikazu,Kashima, Choji
, p. 1719 - 1723 (2007/10/02)
Reduction of indolin-2-ones with lithium aluminium hydride (LAH) or diisobutylaluminium hydride (DIBAL) and desulfurization of indoline-2-thiones with Raney-Ni were investigated.Treatment of indolin-2-ones 1 with LAH or DIBAL yielded indoles 4 and/or indolines 3 in moderate-to-high yields depending on the substituents at N and C(3) of 1.Indoline-2-thiones 2 were desulfurized with Raney-Ni tigive indoles 4 and/or indolines 3.
