132337-03-2

Basic information

• Product Name: p-(cis-2-Chlorocyclopropyl)benzonitrile
• CAS NO: 132337-03-2
• Molecular Weight: 177.633
• Mol File: 132337-03-2.mol

Chemical Properties

• CAS DataBase Reference: p-(cis-2-Chlorocyclopropyl)benzonitrile(CAS DataBase Reference)
• NIST Chemistry Reference: p-(cis-2-Chlorocyclopropyl)benzonitrile(132337-03-2)
• EPA Substance Registry System: p-(cis-2-Chlorocyclopropyl)benzonitrile(132337-03-2)

Safety Data

• Hazardous Substances Data: 132337-03-2(Hazardous Substances Data)

Upstream product

• 132337-10-1 p-(2-Chlorocyclopropyl)benzoyl chloride 
• 132337-09-8 p-(2-Chlorocyclopropyl)benzoic acid 
• 29667-51-4 1-chloro-2-phenylcyclopropane 
• 132337-11-2 p-(2-Chlorocyclopropyl)benzamide 

Relevant articles and documents

Substituent effects on the carbon-13 NMR chemical shifts of cyclopropyl carbons in P-substituted(CIS-and trans-2-chlorocyclopropyl)benzenes

Carbon-13 chemical shifts have been measured for the cyclopropyl carbon atoms of twenty one p-substituted (cis- and trans-2-chlorocyclopropyl)benzenes. The substituent induced chemical shifts (SCS) for the trans derivatives are shifted down field by electron-acceptor substituents and upfield by electron-donating substituents (normal SCS). This SCS trend is the same as those observed for the p-substituted cyclopropylbenzenes, while the SCS range is small because of the decreased polarization of C-1-C-2 bonding due to the attached chlorine atom. For the cis derivatives, SCS for C-1 and C-3(CH 2) carbons were also normal, while no measurable SCS was observed for C-2(CCl). The SCS well fitted with the LSFE equation, indicating that the SCS were controlled mainly by a polar effect, except for C-2(CCl, cis).