13234-71-4

Basic information

• Product Name: 1-Naphthaleneacetic acid, a-cyano-, ethyl ester
• Synonyms: 1-Naphthylcyanoessigsaeureaethylester;α-Naphthyl-(1)-cyanessigsaeure-aethylester;Ethyl 2-Cyano-2-(naphthalen-1-yl)acetate;cyano-[1]naphthyl-acetic acid ethyl ester;Ethyl cyano(1-naphthyl)acetate;Cyan-[1]naphthyl-essigsaeure-aethylester
• CAS NO: 13234-71-4
• Molecular Formula: C15H13NO2
• Molecular Weight: 239.274
• Mol File: 13234-71-4.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-Naphthaleneacetic acid, a-cyano-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Naphthaleneacetic acid, a-cyano-, ethyl ester(13234-71-4)
• EPA Substance Registry System: 1-Naphthaleneacetic acid, a-cyano-, ethyl ester(13234-71-4)

Safety Data

• Hazardous Substances Data: 13234-71-4(Hazardous Substances Data)

Usage

Uses

Ethyl 2-Cyano-2-(naphthalen-1-yl)acetate has been used as a catalyst for the corsslinking of polyesters with styrene.

Upstream product

• 3163-27-7 2-(bromomethyl)naphthalene 
• 86-52-2 1-Chloromethylnaphthalene 
• 105-56-6 ethyl 2-cyanoacetate 
• 90-13-1 1-Chloronaphthalene 
• 90-11-9 1-Bromonaphthalene 
• 90-14-2 1-Iodonaphthalene 
• 132-75-2 naphthalen-1-ylacetonitrile 
• 105-58-8 Diethyl carbonate 

Relevant articles and documents

Phosphine-catalyzed regioselective Michael addition to allenoates

The first phosphine catalysed Michael addition of arylcyanoacetates to allenoates has been developed, and the β-selective products with a quaternary center were obtained in excellent yields. This unusual regioselectivity may open new opportunities to acce

A General Method for the Direct α-Arylation of Nitriles with Aryl Chlorides

The long-standing challenge of developing a general method for the title methodology is met for a broad range of aryl chlorides through the use of bicyclic P(iBuNCH2CH2)3N (1) as a bulky electron-rich ligand for palladium (see scheme, dba = dibenzylideneacetone).

Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery [21]

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