132345-13-2

Upstream product

• 132374-46-0 (-)-N-benzyl-α-(<(1S,2R,4R)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylthio)maleimide 
• 1631-26-1 1-benzyl-1H-pyrrole-2,5-dione 
• 71242-58-5 (1S,2R,4R)-(-)-10-mercaptoisoboneol 
• 132374-44-8 N-benzyl-α-(<(1S,2R,4R)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylthio)succinimide 

Downstream Products

• 144140-87-4 (1S,2R,5S,6R,7R)-(+)-4-benzyl-5-heptyl-10-oxa-4-azatricyclo<5.2.1.0^2,6>dec-8-en-3-one 
• 144140-83-0 (1S,2R,5S,6S,7R)-(+)-4-benzyl-5-(p-tolylsulfonyl)-10-oxa-4-azatricyclo<5.2.1.0^2,6>dec-8-en-3-one 
• 132374-47-1 (1R,2R,6S,7S)-4-Benzyl-5-hydroxy-2-((R)-(1S,2R,4R)-2-hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethanesulfinyl)-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-3-one 
• 132345-20-1 (1R,2S,6R,7S)-4-Benzyl-5-hydroxy-4-aza-tricyclo[5.2.1.0^2,6]dec-8-en-3-one 
• 132436-81-8 (1S,2S,6R,7R)-4-Benzyl-2-((R)-(1S,2R,4R)-2-hydroxy-7,7-dimethyl-bicyclo[2.2.1]hept-1-ylmethanesulfinyl)-4-aza-tricyclo[5.2.1.0^2,6]dec-8-ene-3,5-dione 
• 132345-18-7 (1R,4S)-(-)-N-benzyl-2-exo-(<(1S,2R,4R,R_S)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylsulfinyl)bicyclo<2.2.1>hept-5-ene-2-endo,3-endo-dicarboximide 
• 139730-39-5 (1S,8S,9S,R_S)-11-benzyl-9-<<(1S,2R,4R)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylsulphinyl>-6,11-diaza-7-oxatricyclo<4.3.1>dodecan-10,12-dione 
• 139730-40-8 (R_S)-11-benzyl-8-<<(1S,2R,4R)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylsulphinyl>-6,11-diaza-7-oxatricyclo<4.3.1>dodecan-10,12-dione 
• 132345-19-8 (1R,2S,6S,7R)-(-)-4-benzyl-2-(<(1S,2R,4R,R_S)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylsulfinyl)-10-oxa-4-azatricyclo<5.2.1.0^2,6>dec-8-ene-3,5-dione 
• 132436-82-9 (1R,2S,6S,7S)-(-)-4-benzyl-2-(<(1S,2R,4R,R_S)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylsulfinyl)-10-oxa-4-azatricyclo<5.2.1.0^2,6>dec-8-ene-3,5-dione 
• 132436-83-0 (1R,2R,6R,7S)-(-)-4-benzyl-2-(<(1S,2R,4R,R_S)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylsulfinyl)-10-oxa-4-azatricyclo<5.2.1.0^2,6>dec-8-ene-3,5-dione 
• 132436-84-1 (1S,2R,6R,7R)-(-)-4-benzyl-2-(<(1S,2R,4R,R_S)-2-hydroxy-7,7-dimethylbicyclo<2.2.1>heptan-1-yl>methylsulfinyl)-10-oxa-4-azatricyclo<5.2.1.0^2,6>dec-8-ene-3,5-dione 

Relevant academic research and scientific papers

Asymmetric Diels-Alder Reaction of Optically Active α-(2-exo-Hydroxy-10-bornyl)sulfinylmaleimides and its Application to Optically Active 5-Functionalised Pyrrolines via Retro-Diels-Alder Reaction

Optically pure sulfinylmaleimides 1 have been synthesized.The Diels-Alder reactions of the sulfoxides 1 with various dienes showed high diastereoselectivity.Regioselective reduction of the adducts 4c and 6c followed by desulfination afforded the γ-hydroxy

Powerful Dienophiles for Asymmetric Diels-Alder Reactions: α-(2-exo-Hydroxy-10-bornylsulfinyl)maleimides

Enantiomerically pure N-substituted α-(2-exo-hydroxy-10-bornylsulfinyl)maleimides 1 have been synthesized diastereoselectively, and these dienophiles undergo Diels-Alder reactions readily with furan to give the corresponding cycloadducts with high diastereoselectivity.