132352-99-9Relevant academic research and scientific papers
Generation of hydroxyl radicals from 1-hydroxypyridine-2(1H)-thione and their application to organic synthesis
Boivin, J.,Crepon, E.,Zard, S. Z.
, p. 145 - 150 (2007/10/02)
Upon irradiation with visible light N-hydroxypyridine-2-thione 1 gives rise to hydroxyl radicals which can be used in radical chain reactions involving selective hydrogen abstraction as the key-step. Key Words: N-hydroxypyridine-2-thione / hydroxyl radicals
THE GENERATION AND REACTIVITY OF OXYGEN CENTERED RADICALS FROM THE PHOTOLYSIS OF DERIVATIVES OF N-HYDROXY-2-THIOPYRIDONE
Barton, Derek H. R.,Jaszberenyi, Joseph Cs.,Morrell, Andrew I.
, p. 311 - 314 (2007/10/02)
Oxgen centered radicals, formed by the photolysis of derivatives of N-hydroxy-2-thiopyridone, have been trapped by vinyl ethers.In the case of the benzoyloxy radical, smooth deoxygenation is effected by IIIP compounds.Evidence for the formation of the dimethyltbutylsilyloxy and of the hydroxy radical is also presented.
N-HYDROXY-2-PYRIDINETHIONE: A MILD AND CONVENIENT SOURCE OF HYDROXYL RADICALS
Boivin, Jean,Crepon, Elisabeth,Zard, Samir Z.
, p. 6869 - 6872 (2007/10/02)
N-Hydroxy-2-thiopyridone gives hydroxyl radicals on irradiationm with visible light and these can be incorporated in useful radical chain processes involving hydrogen abstraction.
